What causes painful urination with increased urine concentration?

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If there was unprotected sex one needs to think of sexually transmitted infection. Please get the following tests done.

1. Treponema pallidum hemagglutination (TPHA).
2. Herpes simplex virus (HSV).
3. Herpes simplex virus (HSV).
4. Chlamydia trachomatis.
5. HIV one and two antibodies, screening test.
6. Complete urine culture.

If there is itching you need to think of fungal infection. Ointment candid B for local application and for itching. Take a tablet of Cetirizine once a night.

I hope this has helped you. Thank you.